Shukla, Gaurav ; Alam, Tipu ; Srivastava, Hemant Kumar ; Kumar, Ritush ; Patel, Bhisma K. (2019) Visible-Light-Mediated Ir(III)-Catalyzed Concomitant C3 Oxidation and C2 Amination of Indoles Organic Letters, 21 (10). pp. 3543-3547. ISSN 1523-7060
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Official URL: http://doi.org/10.1021/acs.orglett.9b00887
Related URL: http://dx.doi.org/10.1021/acs.orglett.9b00887
Abstract
A visible-light-mediated concomitant C3 oxidation and C2 amination of indoles has been achieved at room temperature using an Ir (III) photocatalyst. This reaction proceeds without an isatin intermediate via the attack of a singlet oxygen at the C3 position followed by C2 amination leading to difunctionalization of indoles.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 124206 |
| Deposited On: | 08 Nov 2021 11:25 |
| Last Modified: | 08 Nov 2021 11:25 |
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