A Dynamic Chemical Clip in Supramolecular Framework for Sorting Alkylaromatic Isomers using Thermodynamic and Kinetic Preferences

Laha, Subhajit ; Haldar, Ritesh ; Dwarkanath, Nimish ; Bonakala, Satyanarayana ; Sharma, Abhishek ; Hazra, Arpan ; Balasubramanian, Sundaram ; Maji, Tapas Kumar (2021) A Dynamic Chemical Clip in Supramolecular Framework for Sorting Alkylaromatic Isomers using Thermodynamic and Kinetic Preferences Angewandte Chemie International Edition, 60 (36). pp. 19921-19927. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/anie.202106784

Related URL: http://dx.doi.org/10.1002/anie.202106784

Abstract

A dynamic adsorbent that acts like a chemical clip was realized, which sorts alkylaromatic isomers with high selectivity. The design of the chemical clip is based on a supramolecular coordination polymer, and the thermodynamic and kinetic preferences towards the isomers are unveiled by a combinatorial experimental and computational approach.

Item Type:Article
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ID Code:123992
Deposited On:27 Oct 2021 05:11
Last Modified:27 Oct 2021 05:11

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