Nayek, Abhijit ; Drew, Michael G. B. ; Ghosh, Subrata (2003) Convenient route to enantiopure aryl cyclopentanes via Diels-Alder reaction of asymmetric dienes. Total synthesis of (+)-herbertene (I) and (+)-cuparene Tetrahedron, 59 (26). pp. 5175-5181. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4020(03)00807-X
Abstract
A general route for the synthesis of highly substituted aryl cyclopentanes has been developed involving Diels-Alder reaction of asymmetric dienes prepared from (+)-camphoric acid followed by aromatization of the resulting cyclohexene derivatives. Employing this protocol enantiospecific synthesis of (+)-herbertene and (+)-cuparene has been accomplished.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Aromatization; Asymmetric Synthesis; Decarboxylation; Diels-alder Reactions; Terpenes and Terpenoids |
| ID Code: | 12384 |
| Deposited On: | 10 Nov 2010 06:18 |
| Last Modified: | 18 Feb 2011 12:19 |
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