Heterometallic Triply‐Bridging Bis‐ Borylene Complexes

Bag, Ranjit ; Kar, Sourav ; Saha, Suvam ; Gomosta, Suman ; Raghavendra, Beesam ; Roisnel, Thierry ; Ghosh, Sundargopal (2020) Heterometallic Triply‐Bridging Bis‐ Borylene Complexes Chemistry - An Asian Journal, 15 (6). pp. 780-786. ISSN 1861-4728

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Official URL: http://doi.org/10.1002/asia.201901593

Related URL: http://dx.doi.org/10.1002/asia.201901593


Building bridges: Bis-{hydrido(borylene)}, [(μ3-BH)2(μ-H)2{Cp*W(CO)2}2{Fe(CO)2}] and triply-bridging bis-borylene species, [(μ3-BH)2{Cp*W(CO)2}2{M(CO)3}] (M=Fe or Ru) have been isolated and structurally characterized utilizing the coordination sphere of transition metals. In addition, we have synthesized another triply-bridging bis-borylene species, [(μ3-BH)2-(Cp*Rh)2Co2(CO)4(μ-CO)].

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ID Code:123777
Deposited On:13 Oct 2021 07:58
Last Modified:13 Oct 2021 07:58

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