Multipolar polarizabilities and Rydberg states

Krishnagopal, S. ; Narasimhan, S. ; Patil, S. H. (1985) Multipolar polarizabilities and Rydberg states Journal of Chemical Physics, 83 (11). pp. 5772-5777. ISSN 0021-9606

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Official URL: http://doi.org/10.1063/1.449655

Related URL: http://dx.doi.org/10.1063/1.449655

Abstract

We have calculated multipolar polarizabilities for several atoms and ions, using some semiclassical relations and incorporating the correct asymptotic behavior in the electronic densities. We have also obtained simple expressions for penetration energies and nonadiabatic corrections which simplify the analysis of Rydberg states.

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