Crystal structures of Na1/2Ln1/2TiO3 (Ln: La, Eu, Tb)

Ranjan, Rajeev ; Senyshyn, Anatoliy ; Boysen, Hans ; Baehtz, Carsten ; Frey, Friedrich (2007) Crystal structures of Na1/2Ln1/2TiO3 (Ln: La, Eu, Tb) Journal of Solid State Chemistry, 180 (3). pp. 995-1001. ISSN 0022-4596

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Official URL: http://doi.org/10.1016/j.jssc.2006.12.030

Related URL: http://dx.doi.org/10.1016/j.jssc.2006.12.030

Abstract

Neutron powder diffraction studies of Na1/2La1/2TiO3 and Na1/2Tb1/2TiO3, and a synchrotron X-ray powder diffraction study of Na1/2Eu1/2TiO3 have been carried out. Rietveld refinement of the structures confirmed that Na1/2Eu1/2TiO3 and Na1/2Tb1/2TiO3 crystallizes in GdFeO3 type of structure (space group Pbnm). The ambiguity in the literature regarding the crystal structure of Na1/2La1/2TiO3 has been resolved and the correct space group is found to be . A detailed list of refined structural parameters of these compounds is presented for the first time.

Item Type:Article
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ID Code:123049
Deposited On:02 Sep 2021 12:47
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