3d-4f spin interaction and field-induced metamagnetism in RCrO4 (R = Ho, Gd, Lu) compounds

Midya, A. ; Khan, N. ; Bhoi, D. ; Mandal, P. (2014) 3d-4f spin interaction and field-induced metamagnetism in RCrO4 (R = Ho, Gd, Lu) compounds Journal of Applied Physics, 115 (17). 17E114. ISSN 0021-8979

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Official URL: http://doi.org/10.1063/1.4861680

Related URL: http://dx.doi.org/10.1063/1.4861680

Abstract

We observe that the zircon-type RCrO4 (R = Ho, Gd, Lu) compounds exhibit complicated magnetic properties and large magnetic entropy change due to the strong competition between ferromagnetic and antiferromagnetic interactions. For a field change of 7 T, the maximum values of entropy change and refrigerant capacity reach 28 J kg−1 K−1 and 740 J kg−1, respectively, for GdCrO4 whereas the corresponding values for HoCrO4 are 29 J kg−1 K−1 and 550 J kg−1. For GdCrO4 compound, the magnetic entropy change is quite large even at low temperatures well below the ferromagnetic transition.

Item Type:Article
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ID Code:122820
Deposited On:17 Aug 2021 05:01
Last Modified:17 Aug 2021 05:01

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