Samarium(II) iodide promoted carbon-carbon bond fragmentation: a facile route to bridged eight membered rings and 1,3-disubstituted cyclopentanes

Haque, A. ; Ghosh, Subrata (1997) Samarium(II) iodide promoted carbon-carbon bond fragmentation: a facile route to bridged eight membered rings and 1,3-disubstituted cyclopentanes Chemical Communications (21). pp. 2039-2040. ISSN 1359-7345

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Official URL: http://www.rsc.org/Publishing/Journals/CC/article....

Related URL: http://dx.doi.org/10.1039/A705843H

Abstract

Samarium(II) iodide has been found to induce carbon-carbon bond cleavage in a number of bicyclo[2.2.1]heptane derivatives having a 1,4-dicarbonyl moiety under conditions at which the 1,4-dicarbonyl moiety undergoes intramolecular pinacol coupling.

Item Type:	Article
Source:	Copyright of this article belongs to Royal Society of Chemistry.
ID Code:	12273
Deposited On:	10 Nov 2010 05:06
Last Modified:	16 May 2016 21:38

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