Nayek, Abhijit ; Banerjee, Shyamapada ; Sinha, Saikat ; Ghosh, Subrata (2004) Alkoxy group facilitated ring closing metathesis (RCM) of acyclic 1,6-dienes. Convenient synthesis of non-racemic highly substituted cyclopentenols Tetrahedron Letters, 45 (34). pp. 6457-6460. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.06.127
Abstract
Alkoxymethyl groups at the C-5 allylic position of 1,6-dienols have been found to accelerate RCM reactions significantly with the Grubbs' catalyst PhCH=Ru(PCy3)2Cl2. This phenomenon has been used for direct access to highly substituted cyclopentenols, potential intermediates in the synthesis of carbovir, abacavir and BCA.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Asymmetric Synthesis; Cyclopentenes; Metathesis; Nucleosides |
| ID Code: | 12247 |
| Deposited On: | 10 Nov 2010 04:58 |
| Last Modified: | 12 Feb 2011 11:23 |
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