Ganguli, A. K. ; Ganapathi, L. ; Gopalakrishnan, J. ; Rao, C. N. R. (1988) Low-temperature synthesis of novel layered alkali metal-MoO3 bronzes and hexagonal bronzes of the type KyW1-xMoxO3 Journal of Solid State Chemistry, 74 (1). pp. 228-231. ISSN 0022-4596
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002245...
Related URL: http://dx.doi.org/10.1016/0022-4596(88)90349-0
Abstract
A new class of layered alkali metal-MoO3 bronzes, AxMoO3 (A =Li, Na, K, Rb), with nearly the same unit cell parameters as the host oxide has been synthesized by the solid-state reaction of MoO3 with alkali metal iodides around 575 K; LixMoO3 absorbs H2O causing an increase in theb parameter of the unit cell. Hexagonal potassium bronzes of W1-xMoxO3 are synthesized for the first time.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 12246 |
| Deposited On: | 10 Nov 2010 04:58 |
| Last Modified: | 03 Jun 2011 05:13 |
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