Seetharamsingh, B. ; Khairnar, Pankaj V. ; Reddy, D. Srinivasa (2016) First Total Synthesis of Gliomasolide C and Formal Total Synthesis of Sch-725674 Journal of Organic Chemistry, 81 (1). pp. 290-296. ISSN 0022-3263
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Official URL: http://doi.org/10.1021/acs.joc.5b02318
Related URL: http://dx.doi.org/10.1021/acs.joc.5b02318
Abstract
Syntheses of two 14-membered macrolides Sch-725674 and Gliomasolide C are described here. The first total synthesis of Gliomasolide C, the short synthesis of Sch-725674, and regioselective Wacker oxidation of internal olefin are the highlights of this disclosure. In addition, a key macrocycle with orthogonal functionalities was designed and synthesized on a gram scale for the generation of analogues.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society |
| ID Code: | 121938 |
| Deposited On: | 23 Jul 2021 08:55 |
| Last Modified: | 23 Jul 2021 08:55 |
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