Philkhana, Satish Chandra ; Reddy, D. Srinivasa (2017) Total synthesis of natural fregenedadiol and its diacetate, rearranged labdanes with aromatized B ring Tetrahedron Letters, 58 (13). pp. 1262-1264. ISSN 0040-4039
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Official URL: http://doi.org/10.1016/j.tetlet.2017.02.010
Related URL: http://dx.doi.org/10.1016/j.tetlet.2017.02.010
Abstract
Labdane based natural products are most abundant and widely distributed in nature with many compounds exhibiting exceptional biological properties. Fregenedadiol is a bicyclic diterpene isolated from Halimium viscosum and represents a new carbon skeleton fregenedane with its B ring aromatized. Here, we report a total synthesis of this interesting natural product using one-pot Diels-Alder/aromatization sequence and selective hydrogenolysis as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier B.V. |
| ID Code: | 121930 |
| Deposited On: | 23 Jul 2021 08:29 |
| Last Modified: | 30 Jul 2021 07:36 |
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