Luef, Christoph ; Paul, Aloke ; Vizdal, Jiri ; Kroupa, Ales ; Kodentsov, Alexander ; Ipser, Herbert (2006) Thermodynamic Properties and Melting Behavior of Bi–Sn–Zn Alloys Chemical Monthly, 137 (4). pp. 381-395. ISSN 0026-9247
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Official URL: http://doi.org/10.1007/s00706-005-0457-x
Related URL: http://dx.doi.org/10.1007/s00706-005-0457-x
Abstract
The partial and integral enthalpies of mixing of liquid Bi–Sn–Zn alloys were determined at 500°C by a drop calorimetric technique using a Calvet-type microcalorimeter. The ternary interaction parameters in the Bi–Sn–Zn system were fitted using the Redlich-Kister-Muggianu model for substitutional solutions, and isoenthalpy curves of the integral molar enthalpy of mixing at 500°C were constructed. Furthermore, a DSC technique was used to determine the liquidus temperatures in three sections (3, 5, and 7 at.% Zn) as well as the invariant reaction temperature of the ternary eutectic L ⇄ (Bi) + (Sn) + (Zn). The ternary eutectic reaction was found at 135°C.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 121350 |
| Deposited On: | 15 Jul 2021 04:23 |
| Last Modified: | 15 Jul 2021 04:23 |
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