Synthesis of Quinoxalines by a Carbon Nanotube-Gold Nanohybrid-Catalyzed Cascade Reaction of Vicinal Diols and Keto Alcohols with Diamines

Shah, Nimesh ; Gravel, Edmond ; Jawale, Dhanaji V. ; Doris, Eric ; Namboothiri, Irishi N. N. (2014) Synthesis of Quinoxalines by a Carbon Nanotube-Gold Nanohybrid-Catalyzed Cascade Reaction of Vicinal Diols and Keto Alcohols with Diamines ChemCatChem, 7 (1). pp. 57-61. ISSN 1867-3880

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Official URL: http://doi.org/10.1002/cctc.201402782

Related URL: http://dx.doi.org/10.1002/cctc.201402782

Abstract

A one-pot oxidation-condensation method for the synthesis of quinoxalines from readily available benzoins or benzhydrols and 1,2-phenylenediamines or 2,3-diaminopyridine by use of a gold-carbon nanotube nanohybrid as a heterogeneous catalyst is reported. Quinoxalines are formed under mild conditions in air and in excellent yields. The simple and efficient methodology offers a safe and sustainable alternative to conventional acid and/or base-catalyzed thermal processes.

Item Type:Article
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ID Code:121337
Deposited On:14 Jul 2021 11:39
Last Modified:14 Jul 2021 11:39

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