Baiju, Thekke Veettil ; Gravel, Edmond ; Doris, Eric ; Namboothiri, Irishi N.N. (2016) Recent developments in Tsuji-Wacker oxidation Tetrahedron Letters, 57 (36). pp. 3993-4000. ISSN 0040-4039
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Official URL: http://doi.org/10.1016/j.tetlet.2016.07.081
Related URL: http://dx.doi.org/10.1016/j.tetlet.2016.07.081
Abstract
Tsuji-Wacker oxidation is a palladium catalyzed aerobic oxidation of olefins which serves as a potential strategy for the synthesis of carbonyl compounds. Functionalized terminal olefins are prone to oxidation and provide either methyl ketones or aldehydes in accordance with Markovnikov or anti-Markovnikov rules, respectively. Recent investigations have focused on regioselective synthesis of ketones/aldehydes. This digest aims to give an overview on recent progress in catalyst system modifications to achieve regioselectivity in Tsuji-Wacker oxidation. In addition, the influence of substrates bearing directing group on Tsuji-Wacker oxidation is briefly described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Tsuji-Wacker Oxidation; Palladium Catalysis; Markovnikov Addition; Anti-Markovnikov Addition. |
| ID Code: | 121333 |
| Deposited On: | 14 Jul 2021 11:22 |
| Last Modified: | 14 Jul 2021 11:22 |
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