Sugar Binding to VO3+. Synthesis and Structure of a New Mannopyranoside Vanadate

Rajak, Kajal Krishna ; Baruah, Bharat ; Rath, Sankar Prasad ; Chakravorty, Animesh (2000) Sugar Binding to VO3+. Synthesis and Structure of a New Mannopyranoside Vanadate Inorganic Chemistry, 39 (7). pp. 1598-1601. ISSN 0020-1669

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Official URL: http://doi.org/10.1021/ic9910460

Related URL: http://dx.doi.org/10.1021/ic9910460

Abstract

Monoionized-4,6-benzylidine-alpha-D-mannopyranoside has afforded an effectively square pyramidal alkoxide-coordinated VO3+ ester, the benzoylhydrazone of salicylaldehyde being the coligand. Intermolecular O(alcoholic)... O(oxo) hydrogen bonding generates a helical pattern in the crystal lattice.

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