Transfer and control of molecular chirality in the 1 : 2 host–guest supramolecular complex consisting of Mg(ii)bisporphyrin and chiral diols: the effect of H-bonding on the rationalization of chirality

Ikbal, Sk. Asif ; Brahma, Sanfaori ; Rath, Sankar Prasad (2014) Transfer and control of molecular chirality in the 1 : 2 host–guest supramolecular complex consisting of Mg(ii)bisporphyrin and chiral diols: the effect of H-bonding on the rationalization of chirality Chemical Communications, 50 (90). pp. 14037-14040. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C4CC06092J

Related URL: http://dx.doi.org/10.1039/C4CC06092J

Abstract

A clear rationalization of the origin of chirality transfer from an optically active diol guest to an achiral Mg(II)bisporphyrin host in a series of 1 : 2 host–guest supramolecular complexes has been reported here that has so far remained the most outstanding issue for the chirogenic process.

Item Type:Article
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ID Code:120897
Deposited On:07 Jul 2021 05:15
Last Modified:07 Jul 2021 05:15

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