Synthesis of O,O'-alkylenedithiophosphato complexes of cobalt

Tripathi, Umesh ; Singh, Maya (1999) Synthesis of O,O'-alkylenedithiophosphato complexes of cobalt Journal of the Indian Chemical Society, 76 (7). pp. 360-361. ISSN 0019-4522

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Abstract

Complexes of the type [Co{S2PO2G}2] (G = -CMe2CH2CHMe-, -CH2CMe2CH2-, -CMe2CMe2- and -CH2CH2CHMe-) have been prepared by the reaction of CoCl2.6H2O with ammonium dithiophosphates, which on oxidation in dichloromethane solution yield complexes of the type [Co{S2PO2G}3].

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