Corrected spacegroup for M0.5Ti2P3O12 compounds

Senbhagaram, S. ; Guru Row, T. N. ; Umarji, A. M. (1989) Corrected spacegroup for M0.5Ti2P3O12 compounds Solid State Communications, 71 (7). pp. 609-611. ISSN 0038-1098

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/003810...

Related URL: http://dx.doi.org/10.1016/0038-1098(89)90546-2

Abstract

The space group of the low thermal expansion phosphates, belonging to NASICON structural family, having divalent cations has been reassigned as R3̿ based on powder X-ray diffraction studies in the system M0.5Ti2P3O12. This implies further ordered distribution of M2+ cations and vacancies along the hexagonal 'c' direction of NASICON structure.

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