Synthesis and magnetic study of new μ-oxalato dinuclear copper (II) complexes

Mukherjee, Partha Sarathi ; Maji, Tapas Kumar ; Koner, Subratanath ; Rosair, Georgina ; Chaudhuri, Nirmalendu Ray (2001) Synthesis and magnetic study of new μ-oxalato dinuclear copper (II) complexes Indian Journal of Chemistry - Section A: Inorganic, Physical, Theoretical and Analytical Chemistry, 40A (05). pp. 451-455. ISSN 0376-4710

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Abstract

Three new μ-oxalato dinuclear copper(II) complexes [L(H2O)CuOxCu(H2O)L](ClO4) [L = 4-(2-aminoethyl)morpholine (aem), (1), 1-(2-aminoethyl)piperidine (ampp), (2) and 1-(2-aminoethyl)pyrrolidine (ampy), (3)] have been synthesized and characterized by X-ray single crystal analysis (1), IR, thermal analysis and magnetic measurements. Low temperature magnetic measurements of these complexes show the existence of strong anti ferromagnetic interaction between the copper(II) ions.

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