Mondal, Kartik Chandra ; Sengupta, Oindrila ; Mukherjee, Partha Sarathi (2009) Synthesis and characterization of a rare hemiacetalate bridged incomplete dicubane cluster Inorganic Chemistry Communications, 12 (7). pp. 682-685. ISSN 1387-7003
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Official URL: http://doi.org/10.1016/j.inoche.2009.05.027
Related URL: http://dx.doi.org/10.1016/j.inoche.2009.05.027
Abstract
Reaction of 2-pyridinecarboxaldehyde [(Py)CHO] with Cu(NO3)2·2.5H2O in the presence of 4-aminopyridine and NaN3 in MeOH lead to an incomplete double-cubane [Cu4{PyCH(O)(OMe)}4(N3)4] (1) in 87% isolated yield, representing a rare type of metal cluster containing bridging hemiacetalate ligand [pyCH(O)(OMe)]−1 which was characterized by single crystal structure analysis and variable temperature magnetic behavior.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Antiferromagnetic; Crystal Structure; Azide; Copper(II). |
| ID Code: | 119999 |
| Deposited On: | 21 Jun 2021 11:34 |
| Last Modified: | 21 Jun 2021 11:34 |
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