Sureshan, Kana M ; Miyasou, Tomomi ; Watanabe, Yutaka (2004) Crystal structure of 1l-1,2:4,5-di-O-isopropylidene-allo-inositol; A comparison of its conformation in solid and solution states Carbohydrate Research, 339 (8). pp. 1551-1555. ISSN 0008-6215
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Official URL: http://doi.org/10.1016/j.carres.2004.03.031
Related URL: http://dx.doi.org/10.1016/j.carres.2004.03.031
Abstract
The X-ray crystal structure of 1l-1,2:4,5-di-O-isopropylidene-allo-inositol, is described. The inositol ring deviate slightly from the ideal chair conformation to a flattened chair. A comparison of its conformation in solution with that in solid was made by the use of 1H NMR. This conformational analysis revealed that the title compound adopts similar conformations in solid state and in solution in low polar solvents like benzene and CHCl3 while in high polar solvents such as Me2SO, the solid state conformation is not retained.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 119813 |
| Deposited On: | 17 Jun 2021 08:20 |
| Last Modified: | 17 Jun 2021 08:20 |
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