ANTIMONY(III) COMPLEXES OF 2-(N-SALICYLIDENE)-5-CHLOROBENZOPHENONE: SYNTHESIS, SPECTROSCOPIC STUDIES AND REACTIVITY WITH RESPECT TO SULFUR DONOR LIGANDS

Singh, M. S. ; Rao, K. Prasada (1998) ANTIMONY(III) COMPLEXES OF 2-(N-SALICYLIDENE)-5-CHLOROBENZOPHENONE: SYNTHESIS, SPECTROSCOPIC STUDIES AND REACTIVITY WITH RESPECT TO SULFUR DONOR LIGANDS Main Group Metal Chemistry, 21 (1). pp. 1-8. ISSN 0792-1241

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Official URL: http://doi.org/10.1515/MGMC.1998.21.1.1

Related URL: http://dx.doi.org/10.1515/MGMC.1998.21.1.1

Abstract

ichloro, chlorobis and tris [2-(N-salicylidene)-5-chlorobenzophenone] derivatives of antimony(lll) have been synthesised by the reactions of antimony trichloride with the sodium salt of 2-(N-salicylidene)-5-chlorobenzophenone (prepared insitu) in 1:1, 1:2 and 1:3 molar ratios, respectively The substitution reactions of these newly synthesised chloro derivatives have been studied with alkyl xanthates. All these compounds are characterised by elemental analyses, molecular weight measurements and spectroscopic (IR, 1H and 13C NMR) studies.

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