A novel one-pot procedure for the synthesis of stable dioxadiazastannepines and dioxadiazasilepines

Singh, M.S. ; Singh, A.K. (2005) A novel one-pot procedure for the synthesis of stable dioxadiazastannepines and dioxadiazasilepines Tetrahedron Letters, 46 (2). pp. 315-317. ISSN 0040-4039

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Official URL: http://doi.org/10.1016/j.tetlet.2004.11.031

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.11.031

Abstract

A novel synthetic approach to seven-membered silicon- and tin-containing heterocycles has been developed. 5,6-Diaryl-1,3,4,7,2-dioxadiazastannepines 3a–l and 5,6-diaryl-1,3,4,7,2-dioxadiazasilepines 4a–l were prepared in one pot from vicinal dioximes 1a–d and diorganodichlorostannanes and diorganodichlorosilanes via dianion intermediate 2 in good yields.

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