Generation of the [NiFe] Hydrogenase Active Site (Sulfur's the One!)

Glass, Richard S. ; Paschos, Athanasios ; Reissmann, Stephanie ; Singh, M. S. ; Wang, Haofan ; Böck, August (2005) Generation of the [NiFe] Hydrogenase Active Site (Sulfur's the One!) Phosphorus, Sulfur, and Silicon and the Related Elements, 180 (5-6). pp. 1183-1185. ISSN 1042-6507

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Official URL: http://doi.org/10.1080/10426500590910774

Related URL: http://dx.doi.org/10.1080/10426500590910774

Abstract

Chemical and biochemical methods were used to unravel the unprecedented pathway by which the CN ligands of iron in [NiFe] hydrogenase are introduced. Carbamoyl phosphate is the one carbon precursor of these ligands, and reactions involving a protein cysteinyl sulfur are key for processing this precursor into CN ligands.

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Deposited On:16 Jun 2021 07:38
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