Chowdhury, Sushobhan ; Chanda, Tanmoy ; Gupta, Ashutosh ; Koley, Suvajit ; Ramulu, B. Janaki ; Jones, Raymond C. F. ; Singh, Maya Shankar (2014) Indium(0)-Mediated C sp 3-S/O Cross-Coupling Approach Towards the Regioselective Alkylation of α-Enolic Esters/Dithioesters: A Mechanistic Insight European Journal of Organic Chemistry, 2014 (14). pp. 2964-2971. ISSN 1434-193X
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Official URL: http://doi.org/10.1002/ejoc.201301788
Related URL: http://dx.doi.org/10.1002/ejoc.201301788
Abstract
An indium(0)-mediated Curn:x-wiley:1434193X:media:EJOC201301788:tex2gif-inf-4–S/O cross-coupling reaction that proceeds without added co-catalyst or promoter leads to the highly regioselective alkylation of α-enolic acetate/dithioacetate systems. The selectivity for C-, S-, or O-alkylation is dependent on the nucleophilic behavior of α-enolic acetate/dithioacetate system and was further supported by DFT calculations.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 119632 |
| Deposited On: | 15 Jun 2021 11:25 |
| Last Modified: | 24 Jun 2021 10:31 |
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