Mukherjee, Partha Sarathi ; Maji, Tapas Kumar ; Mostafa, Golam ; Mallah, Talal ; Chaudhuri, Nirmalendu Ray (2000) The First Structurally Alternating Copper(II) Chain with Alternate Single End-on and End-to-End Azido Bridging: A Synthesis, Crystal Structure, and Low-Temperature Magnetic Study Inorganic Chemistry, 39 (22). pp. 5147-5150. ISSN 0020-1669
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Official URL: http://doi.org/10.1021/ic000507a
Related URL: http://dx.doi.org/10.1021/ic000507a
Abstract
A novel 1-D chain of Cu(II) with alternate single end-on and single end-to-end azido bridge having a very high Cu - N3(1,1) - Cu bond angle (129.98°) has been synthesized and characterized, which shows an intra-chain antiferronmagnetic interaction (J = -11.5 cm-1 for end-on bridge and -2.7 cm-1 for end-to-end bridge).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 119601 |
| Deposited On: | 14 Jun 2021 13:56 |
| Last Modified: | 14 Jun 2021 13:56 |
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