Dual role of azide in the formation of a 3D coordination polymer containing bridging 5-pyrimidinecarboxylate

Sengupta, Oindrila ; Chakrabarty, Rajesh ; Mukherjee, Partha Sarathi (2007) Dual role of azide in the formation of a 3D coordination polymer containing bridging 5-pyrimidinecarboxylate Dalton Transactions (40). p. 4514. ISSN 1477-9226

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Official URL: http://doi.org/10.1039/B711346C

Related URL: http://dx.doi.org/10.1039/B711346C

Abstract

A new 3D framework [Mn4(5-pmc)4(1,1-N3)4]n (1) composed of a rare MnII4 square as the repeating secondary building unit, representing the first coordination polymer of 5-pyrimidinecarboxylate (5-pmc) has been successfully synthesized and characterized by X-ray single crystal structure analysis.

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