Self-Assembly of a Nanoscopic Pt12Fe12Heterometallic Open Molecular Box Containing Six Porphyrin Walls

Bar, Arun Kumar ; Chakrabarty, Rajesh ; Mostafa, Golam ; Mukherjee, Partha Sarathi (2008) Self-Assembly of a Nanoscopic Pt12Fe12Heterometallic Open Molecular Box Containing Six Porphyrin Walls Angewandte Chemie International Edition, 47 (44). pp. 8455-8459. ISSN 1433-7851

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Official URL: http://doi.org/10.1002/anie.200803543

Related URL: http://dx.doi.org/10.1002/anie.200803543

Abstract

Self-assembly of 5,10,15,20-tetrakis(4-pyridyl)porphyrin with two equivalents of cis-[(dppf)Pt(OTf)2] (dppf=1,1′-bis(diphenylphosphino)ferrocene; OTf=CF3SO3−) yielded the first open molecular box containing six porphyrin walls (see scheme) and an internal open void volume of around 43 550 Å3.

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