Bar, Arun Kumar ; Mostafa, Golam ; Mukherjee, Partha Sarathi (2010) A Pd6Molecular Cage via Multicomponent Self-Assembly Incorporating Both Neutral and Anionic Linkers Inorganic Chemistry, 49 (17). pp. 7647-7649. ISSN 0020-1669
Full text not available from this repository.
Official URL: http://doi.org/10.1021/ic101139s
Related URL: http://dx.doi.org/10.1021/ic101139s
Abstract
A Pd6 molecular cage [{(tmen)Pd}6(bpy)3(tma)2](NO3)6 [1; where tmen = N,N,N′,N′-tetramethylethylene diamine, bpy = 4,4′-bipyridyl, and H3tma = trimesic acid] was prepared via the template-free three-component self-assembly of a cis-blocked palladium(II) acceptor in combination with a tricarboxylate and a dipyridyl donor. Complex 1 represents the first example of a 3D palladium(II) cage of defined shape incorporating anionic and neutral linkers. Guest-induced exclusive formation of this cage was also monitored by an NMR study.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 118865 |
| Deposited On: | 02 Jun 2021 19:00 |
| Last Modified: | 02 Jun 2021 19:00 |
Repository Staff Only: item control page
