Self-Assembly of an Octanuclear Platinum(II) Tetragonal Prism from a New PtII4Organometallic Star-Shaped Acceptor and Its Nitroaromatic Sensing Study

Shanmugaraju, Sankarasekaran ; Jadhav, Harshal ; Patil, Yogesh P. ; Mukherjee, Partha Sarathi (2012) Self-Assembly of an Octanuclear Platinum(II) Tetragonal Prism from a New PtII4Organometallic Star-Shaped Acceptor and Its Nitroaromatic Sensing Study Inorganic Chemistry, 51 (24). pp. 13072-13074. ISSN 0020-1669

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Official URL: http://doi.org/10.1021/ic301716y

Related URL: http://dx.doi.org/10.1021/ic301716y

Abstract

[2 + 4] self-assembly of a pyrene-functionalized PtII8 tetragonal prism (2) is achieved using a newly designed star-shaped organometallic acceptor (1) in combination with an amide-based “clip” donor (L). The propensity of this prism (2) as a selective sensor for nitroaromatics (2,4-dinitrotoluene, 1,3,5-trinitrotoluene, and picric acid), which are the chemical constituents of many commercial explosives, has been examined.

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