Acharyya, Koushik ; Mukherjee, Sandip ; Mukherjee, Partha Sarathi (2013) Molecular Marriage through Partner Preferences in Covalent Cage Formation and Cage-to-Cage Transformation Journal of the American Chemical Society, 135 (2). pp. 554-557. ISSN 0002-7863
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Official URL: http://doi.org/10.1021/ja310083p
Related URL: http://dx.doi.org/10.1021/ja310083p
Abstract
Unprecedented self-sorting of three-dimensional purely organic cages driven by dynamic covalent bonds is described. Four different cages were first synthesized by condensation of two triamines and two dialdehydes separately. When a mixture of all the components was allowed to react, only two cages were formed, which suggests a high-fidelity self-recognition. The issue of the preference of one triamine for a particular dialdehyde was further probed by transforming a non-preferred combination to either of the two preferred combinations by reacting it with the appropriate triamine or dialdehyde.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 118772 |
| Deposited On: | 29 May 2021 15:43 |
| Last Modified: | 29 May 2021 15:43 |
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