Shape and size directed self-selection in organic cage formation

Acharyya, Koushik ; Mukherjee, Partha Sarathi (2015) Shape and size directed self-selection in organic cage formation Chemical Communications, 51 (20). pp. 4241-4244. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C5CC00075K

Related URL: http://dx.doi.org/10.1039/C5CC00075K

Abstract

The selective formation of a single isomer of a [3+2] self-assembled organic cage from a reaction mixture of an unsymmetrical aldehyde and a flexible amine is discussed. The experimental and theoretical findings suggest that in such a process, the geometric features of the aldehyde play a key role.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:118703
Deposited On:28 May 2021 07:33
Last Modified:28 May 2021 07:33

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