Mukherjee, Arup ; Sen, Tamal K. ; Baskaran, Sambath ; Sivasankar, Chinnappan ; Mandal, Swadhin K. (2015) Slow hydrolysis of an organozirconium complex: The first polyoxometallic heptanuclear zirconium oxide Journal of Organometallic Chemistry, 775 . pp. 76-79. ISSN 0022-328X
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Official URL: http://doi.org/10.1016/j.jorganchem.2014.10.022
Related URL: http://dx.doi.org/10.1016/j.jorganchem.2014.10.022
Abstract
Herein we report controlled hydrolysis of an organozirconium trimetallic complex, [Cp*2(Me)Zr(μ-O)Zr(NMe2)2(μ-O)Zr(Me)Cp*2] (Cp* = η5-C5Me5) by slow hydrolysis pathway inside the glovebox resulting in unexpected formation of the first heptanuclear zirconium complex. The basic core of this zirconium complex is reminiscent of a butterfly like structure.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier B.V.. |
| ID Code: | 118403 |
| Deposited On: | 20 May 2021 18:47 |
| Last Modified: | 20 May 2021 18:47 |
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