Abnormal N-heterocyclic carbene palladium complex: living catalyst for activation of aryl chlorides in Suzuki–Miyaura cross coupling

Sau, Samaresh Chandra ; Santra, Subhankar ; Sen, Tamal K. ; Mandal, Swadhin K. ; Koley, Debasis (2012) Abnormal N-heterocyclic carbene palladium complex: living catalyst for activation of aryl chlorides in Suzuki–Miyaura cross coupling Chemical Communications, 48 (4). pp. 555-557. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/C1CC15732A

Related URL: http://dx.doi.org/10.1039/C1CC15732A

Abstract

Palladium complexes bearing abnormal N-heterocyclic carbene were used as catalysts in Suzuki–Miyaura cross coupling of aryl chlorides at 25 °C. The catalyst remained active for 10 successive catalytic runs and can activate 4-chlorotoluene at 25 °C with 0.01 mol% catalyst loading resulting in a TON of 9500 within 6 h.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:118368
Deposited On:20 May 2021 14:26
Last Modified:20 May 2021 14:26

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