Phenalenyl-Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design a Catalyst

Sen, Tamal K. ; Mukherjee, Arup ; Modak, Arghya ; Ghorai, Pradip Kr. ; Kratzert, Daniel ; Granitzka, Markus ; Stalke, Dietmar ; Mandal, Swadhin K. (2011) Phenalenyl-Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design a Catalyst Chemistry - A European Journal, 18 (1). pp. 54-58. ISSN 0947-6539

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Official URL: http://doi.org/10.1002/chem.201103224

Related URL: http://dx.doi.org/10.1002/chem.201103224

Abstract

Phenalenyl in action: The cationic state of the phenalenyl system can be used to design Lewis acidic catalysts. The phenalenyl backbone can tune the energy of the lowest unoccupied molecular orbital (LUMO) of the molecule, which in turn controls the catalytic activity in the ring-opening polymerization of cyclic esters.

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Deposited On:20 May 2021 14:23
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