Hota, Pradip Kumar ; Maji, Subir ; Ahmed, Jasimuddin ; Rajendran, N. M. ; Mandal, Swadhin K. (2020) NHC-catalyzed silylative dehydration of primary amides to nitriles at room temperature Chemical Communications, 56 (4). pp. 575-578. ISSN 1359-7345
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Official URL: http://doi.org/10.1039/C9CC08413D
Related URL: http://dx.doi.org/10.1039/C9CC08413D
Abstract
Herein we report an abnormal N-heterocyclic carbene catalyzed dehydration of primary amides in the presence of a silane. This process bypasses the energy demanding 1,2-siloxane elimination step usually required for metal/silane catalyzed reactions. A detailed mechanistic cycle of this process has been proposed based on experimental evidence along with computational study.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 118207 |
| Deposited On: | 19 May 2021 06:59 |
| Last Modified: | 19 May 2021 06:59 |
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