Chakraborty, Soumi ; Das, Arpan ; Ahmed, Jasimuddin ; Barman, Sayani ; Mandal, Swadhin K. (2020) Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2 functionalization Chemical Communications, 56 (89). pp. 13788-13791. ISSN 1359-7345
Full text not available from this repository.
Official URL: http://doi.org/10.1039/D0CC05348A
Related URL: http://dx.doi.org/10.1039/D0CC05348A
Abstract
Herein, we report the synthesis of a Cr(III)-complex bearing a redox non-innocent phenalenyl-based ligand and its use as a catalyst for SET mediated hydrosilylative reduction of carbon dioxide towards formylation of primary amides under mild conditions. A preliminary mechanistic picture for this transformation has been proposed by isolation and characterization of several reactive intermediates.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 118192 |
| Deposited On: | 18 May 2021 11:07 |
| Last Modified: | 18 May 2021 11:07 |
Repository Staff Only: item control page
