An efficient controlled synthesis of bent-core oligoarenes and heteroarenes through ring transformation of 2H-pyran-2-ones

Sil, Diptesh ; Goel, Atul ; Ram, Vishnu Ji (2003) An efficient controlled synthesis of bent-core oligoarenes and heteroarenes through ring transformation of 2H-pyran-2-ones Tetrahedron Letters, 44 (16). pp. 3363-3365. ISSN 0040-4039

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Official URL: http://doi.org/10.1016/S0040-4039(03)00575-6

Related URL: http://dx.doi.org/10.1016/S0040-4039(03)00575-6

Abstract

A general controlled synthesis of oligoarenes and heteroarenes through base-catalyzed ring transformation of 6-aryl-4-(pyrrolidin-1-yl)-2H-pyran-2-one-3-carbonitriles (1a–d) and methyl 6-aryl-4-methylthio-2H-pyran-2-one-3-carboxylates (1e–h) is described. This procedure offers flexibility in the fabrication of diverse oligoarene ring systems in a controlled fashion.

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