Ajayaghosh, Ayyappanpillai ; Varghese, Reji ; George, Subi Jacob ; Vijayakumar, Chakkooth (2006) Transcription and Amplification of Molecular Chirality to Oppositely Biased Supramolecular π Helices Angewandte Chemie International Edition, 45 (7). pp. 1141-1144. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/anie.200503142
Related URL: http://dx.doi.org/10.1002/anie.200503142
Abstract
Let's twist again: Transcription of molecular chirality from common stereogenic centers to amplified supramolecular chirality during the coassembly of gel‐forming π‐conjugated molecules by inverted helicity results in the formation of longitudinally fused M and P helices. This “sergeants and soldiers” approach to coassembly under stereomutation has been confirmed by CD and AFM techniques (see picture).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Chirality; Gels; Helical Structures; Scanning Probe Microscopy; Self‐Assembly. |
| ID Code: | 117796 |
| Deposited On: | 04 May 2021 04:03 |
| Last Modified: | 04 May 2021 04:03 |
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