Katsonis, Nathalie ; Xu, Hong ; Haak, Robert M. ; Kudernac, Tibor ; Tomović, Željko ; George, Subi ; Van der Auweraer, Mark ; Schenning, Albert P. H. J. ; Meijer, E. W. ; Feringa, Ben L. ; De Feyter, Steven (2008) Emerging Solvent-Induced Homochirality by the Confinement of Achiral Molecules Against a Solid Surface Angewandte Chemie International Edition, 47 (27). pp. 4997-5001. ISSN 1433-7851
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Official URL: http://doi.org/10.1002/anie.200800255
Related URL: http://dx.doi.org/10.1002/anie.200800255
Abstract
One hand mapping: By means of scanning tunneling microscopy, solvent‐induced homochirality is shown to emerge in self‐assembled monolayers of achiral molecules at the liquid–solid interface (see picture). The chirality of the solvent directs the macroscopic chirality of the monolayer. The dynamics of the monolayer structure as it evolves towards homochirality are probed by time‐dependent measurements.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc. |
| Keywords: | Chirality; Liquid-Solid Interfaces; Scanning Probe Microscopy; Self‐Assembly; Supramolecular Chemistry. |
| ID Code: | 117788 |
| Deposited On: | 03 May 2021 10:53 |
| Last Modified: | 03 May 2021 10:53 |
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