Spectroscopic Probing of the Dynamic Self-Assembly of an Amphiphilic Naphthalene Diimide Exhibiting Reversible Vapochromism

Kumar, Mohit ; George, Subi J. (2011) Spectroscopic Probing of the Dynamic Self-Assembly of an Amphiphilic Naphthalene Diimide Exhibiting Reversible Vapochromism Chemistry - A European Journal, 17 (40). pp. 11102-11106. ISSN 0947-6539

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Official URL: http://doi.org/10.1002/chem.201101642

Related URL: http://dx.doi.org/10.1002/chem.201101642

Abstract

Fluorescent nose: The reversible “turn‐on” vapochromism of a self‐assembled amphiphilic naphthalene diimide derivative in solution and film states is presented. This property was found to be due to solvent–vapor‐responsive, dynamic reorganization in molecular packing in going from J‐type aggregates (blue fluorescent; see left‐hand side of scheme) to preassociated H‐type excimer states, with enhanced green fluorescence.

Item Type:Article
Source:Copyright of this article belongs to John Wiley & Sons, Inc.
Keywords:Amphiphiles; Excimer; Naphthalene Diimide; Self‐Assembly; Vapochromism.
ID Code:117770
Deposited On:03 May 2021 09:18
Last Modified:03 May 2021 09:18

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