Above room temperature spin transition in a metallo-supramolecular coordination oligomer/polymer

Rajadurai, Chandrasekar ; Fuhr, Olaf ; Kruk, Robert ; Ghafari, Mohammed ; Hahn, Horst ; Ruben, Mario (2007) Above room temperature spin transition in a metallo-supramolecular coordination oligomer/polymer Chemical Communications (25). p. 2636. ISSN 1359-7345

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Official URL: http://doi.org/10.1039/B702468A

Related URL: http://dx.doi.org/10.1039/B702468A

Abstract

By use of a metallo-supramolecular concept, a linear iron(II) coordination chain [FeII(L)]n(BF4)2n (L = 1,4-bis(1,2′:6′,1″-bispyrazolylpyridin-4′-yl)benzene) was rationally designed and synthesized. The molecular chain shows a reversible spin transition at 323 K with a ca. 10 K wide hysteresis loop.

Item Type:Article
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ID Code:117446
Deposited On:23 Apr 2021 08:58
Last Modified:23 Apr 2021 08:58

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