The intermolecular β-coupling of cyclic enones with activated alkenes and alkynes: Unexpected β-alkoxy elimination from a 4-alkoxy-2-alkyl-1-hydroxy-cyclopentenyl radical

Pandey, Ganesh ; Ghorai, Manas K. ; Hajra, Saumen (1998) The intermolecular β-coupling of cyclic enones with activated alkenes and alkynes: Unexpected β-alkoxy elimination from a 4-alkoxy-2-alkyl-1-hydroxy-cyclopentenyl radical Tetrahedron Letters, 39 (45). pp. 8341-8344. ISSN 0040-4039

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Official URL: http://doi.org/10.1016/S0040-4039(98)01839-5

Related URL: http://dx.doi.org/10.1016/S0040-4039(98)01839-5

Abstract

Intermolecular β-coupling of cyclic enones with activated alkenes or alkynes and an unexpected β-alkoxide elimination from 17 during the extension of this strategy towards the synthesis of optically pure prostaglandin analogues by the coupling of 16 and 11 is reported.

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