Aldolases as Leitmotiv - A Nonenzymatic Domino Aldol Reaction Triggered by Zinc Bisenolate and Polyenolate (ate) Complexes

Schmittel, Michael ; Ghorai, Manas K. (2001) Aldolases as Leitmotiv - A Nonenzymatic Domino Aldol Reaction Triggered by Zinc Bisenolate and Polyenolate (ate) Complexes Synlett, 2001 (12). pp. 1992-1994. ISSN 0936-5214

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Official URL: http://doi.org/10.1055/s-2001-18766

Related URL: http://dx.doi.org/10.1055/s-2001-18766

Abstract

A new zinc(II) mediated sequential aldol reaction is described for the diastereoselective one-pot synthesis of tetrahydropyran-2,4-diols. The dependence of the yield on the ratio Zn2 +/enolate proposes that zinc(II) polyenolate and ate complexes may be involved.

Item Type:Article
Source:Copyright of this article belongs to Georg Thieme Verlag KG.
ID Code:117140
Deposited On:15 Apr 2021 08:12
Last Modified:15 Apr 2021 08:12

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