Regioselective Addition of 1,3-Dicarbonyl Dianions to Carbonyl Compounds: One Pot Lactonization and Ketalization of δ-Hydroxy-β-keto Esters to Protected Pyrone Derivatives

Ghorai, Manas K. ; Halder, Sandipan ; Samanta, Sauvik (2012) Regioselective Addition of 1,3-Dicarbonyl Dianions to Carbonyl Compounds: One Pot Lactonization and Ketalization of δ-Hydroxy-β-keto Esters to Protected Pyrone Derivatives Australian Journal of Chemistry, 65 (9). p. 1262. ISSN 0004-9425

Full text not available from this repository.

Official URL: http://doi.org/10.1071/CH12062

Related URL: http://dx.doi.org/10.1071/CH12062

Abstract

A simple and efficient strategy for the synthesis of 6-substituted-2-pyrone derivatives, by BF3·OEt2 mediated one pot cyclization and keto-protection of δ-hydroxy-β-keto esters, obtained via regioselective addition of 1,3-dicarbonyl dianion of ethyl acetoacetate to aldehydes and ketones is described.

Item Type:Article
Source:Copyright of this article belongs to CSIRO.
ID Code:117117
Deposited On:15 Apr 2021 08:00
Last Modified:15 Apr 2021 08:00

Repository Staff Only: item control page