Mallick, Arijit ; Saha, Subhadeep ; Pachfule, Pradip ; Roy, Sudip ; Banerjee, Rahul (2010) Selective CO2 and H2 adsorption in a chiral magnesium-based metal organic framework (Mg-MOF) with open metal sites Journal of Materials Chemistry, 20 (41). p. 9073. ISSN 0959-9428
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Official URL: http://doi.org/10.1039/C0JM01125H
Related URL: http://dx.doi.org/10.1039/C0JM01125H
Abstract
A rare porous magnesium-based metal–organic framework, Mg-MOF-1 [Mg(3,5-PDC)(H2O)], was synthesized solvothermally in DMF. Structural determination by X-ray single-crystal diffraction technique reveals that this chiral MOF (space group P6122) is constructed by helical assembly of Mg2+ ions with achiral 3,5-pyridine dicarboxylates and coordinating water molecules, to form a three-dimensional framework with parallel hexagonal channels.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to The Royal Society of Chemistry. |
| ID Code: | 115914 |
| Deposited On: | 16 Mar 2021 12:08 |
| Last Modified: | 16 Mar 2021 12:08 |
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