Pachfule, Pradip ; Banerjee, Rahul (2011) Porous Nitrogen Rich Cadmium-Tetrazolate Based Metal Organic Framework (MOF) for H2and CO2Uptake Crystal Growth & Design, 11 (12). pp. 5176-5181. ISSN 1528-7483
Full text not available from this repository.
Official URL: http://doi.org/10.1021/cg201054f
Related URL: http://dx.doi.org/0.1021/cg201054f
Abstract
The highly porous nitrogen rich metal organic framework [Cd3(4-TP)6] (Cd-4TP-1) was synthesized solvothermally from the predesigned organic building block 4-tetrazole pyridine (4-TP) and Cd(II) as metal center using DMF as solvent. Cd-4TP-1 has a three-dimensional porous architecture where all the binding sites of Cd(II) are exclusively occupied by the nitrogen atoms from the μ2-tetrazolyl group or the pyridyl functionality of the 4-TP ligands. Cd-4TP-1 has Brunauer–Emmett–Teller (BET) and Langmuir surface areas of 472.2 and 728.6 m2/g, respectively, and shows 1.1 wt % H2 (77 K) and 2.7 mmol/g CO2 uptake (273 K).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| Keywords: | Metals; Ligands; Metal Organic Frameworks; Nitrogen,Solvents. |
| ID Code: | 115913 |
| Deposited On: | 16 Mar 2021 12:05 |
| Last Modified: | 16 Mar 2021 12:05 |
Repository Staff Only: item control page
