Hydrogen bond directed honeycomb-like porous network structure of tris(bipyridyl-glycoluril)cobalt(iii) chloride

Kawade, Vitthal A. ; Kumbhar, Avinash S. ; Erxleben, Andrea ; Pachfule, Pradip ; Banerjee, Rahul (2011) Hydrogen bond directed honeycomb-like porous network structure of tris(bipyridyl-glycoluril)cobalt(iii) chloride CrystEngComm, 13 (17). p. 5289. ISSN 1466-8033

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Official URL: http://doi.org/10.1039/C1CE05376K

Related URL: http://dx.doi.org/10.1039/C1CE05376K

Abstract

The [Co(bpg)3]Cl3 complex (1), where bpg = 4b, 5, 7, 7a-tetrahydro-4b,7a-epiminomethan-oimino-6H-imidazo [4,5-f][1,10]-phenanthroline-6,13-dione has been synthesized and characterized by various spectroscopic techniques and single crystal X-ray diffraction. The combination of bipyridyl-glycoluril (bpg) ligands and cobalt ion self-organise to form a honeycomb-like porous network structure resulting in the formation of zeolite like channels which adsorb gases, is described.

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ID Code:115911
Deposited On:16 Mar 2021 11:35
Last Modified:16 Mar 2021 11:35

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