Saha, Subhadeep ; Schön, Eva-Maria ; Cativiela, Carlos ; Díaz Díaz, David ; Banerjee, Rahul (2013) Proton-Conducting Supramolecular Metallogels from the Lowest Molecular Weight Assembler Ligand: A Quote for Simplicity Chemistry - A European Journal, 19 (29). pp. 9562-9568. ISSN 0947-6539
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Official URL: http://doi.org/10.1002/chem.201204542
Related URL: http://dx.doi.org/10.1002/chem.201204542
Abstract
Oxalic acid has been proven to be the lowest molecular weight organic ligand able to form robust supramolecular metallogel networks in the presence of metal salts. In particular, two novel multifunctional metallogels were readily prepared at room temperature by simple mixing of stock solutions of CuII acetate monohydrate or CuII perchlorate hexahydrate and oxalic acid dihydrate. Formation of different polymorphs and unprecedented proton conduction under anhydrous conditions were also demonstrated with some of these materials.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley & Sons, Inc.. |
| Keywords: | Copper; Low‐Molecular‐Weight Ligands; Metallogels; Proton Conductivity; Supramolecular Chemistry. |
| ID Code: | 115860 |
| Deposited On: | 16 Mar 2021 09:19 |
| Last Modified: | 16 Mar 2021 09:19 |
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